Amazing Spider-Man (1963) 79-A

"To Prowl No More!"

Spider-Man faces neophyte would-be vigilante, the Prowler on the rooftops of New York. Caught off-guard by a sneaky gas attack, Spidey lets the Prowler furtively slip away.
As the Prowler was in the process of ripping off the Daily Bugle safe, he was confronted by Peter Parker, who used his initiative to fake falling out a window to get a chance to change into his Spider-duds.

Wracked with guilt and contrition over Parker's apparent death, Hobie Brown elects to capture Spidey and bring him in to the police as the Prowler.

Hobie learns fast, the hard way, that he is nowhere near strong enough or experienced to deal with the wall-crawler at the top of his game. When Spidey discovers that the Prowler is just a misguided teenager, not much younger than himself he deigns to give him the benefit of a second chance.