Superboy in "The Laws that Backfired"
Smallville City Councilman Henry Mathers convinces the Smallville government to abolish their police force and fire department in favor of using Superboy, to save money. However Superboy reads all the laws on the city books and discovers that Smallville is about to cease to exist.
Aqauaman in "Aquaman Leaves the Sea"
Johnny Quick in "Johnny Slow"
Green Arrow in "The Remote-Controlled Archers"