Collecting material from Amazing Fantasy (1962) #15, Amazing Spider-Man (1963) #1-17 and Amazing Spider-Man Annual #1.
"Spider-Man!",
"Spider-Man: Freak! Public Menace!",
"The Chameleon!",
"Duel to the Death with the Vulture!",
"The Uncanny Threat of the Terrible Tinkerer!",
"The Strangest Foe of All Time... Doctor Octopus",
"Nothing Can Stop the... Sandman!",
"Marked for Destruction by Dr. Doom!",
"Face-to-Face with... The Lizard!",
"The Return of the Vulture",
"The Terrible Threat of the Living Brain!",
"Spider-Man Tackles the Torch!",
"The Man Called Electro!",
"The Enforcers!",
"Turning Point",
"Unmasked by Dr. Octopus!",
"The Menace of... Mysterio!",
"The Grotesque Adventure of the Green Goblin",
"Kraven the Hunter!",
"The Sinister Six!",
"A Gallery of Spider-Man's Most Famous Foes!",
"The Secrets of Spider-Man!",
"How Stan Lee and Steve Ditko Create Spider-Man!",
"Duel with Daredevil!",
"The Return of the Green Goblin!"
*In 1962, in the pages of a comic book slated for cancellation, Stan Lee and Steve Ditko gave birth to one of the most enduring icons in American popular culture: the Amazing Spider-Man! Turning the concept of a super hero on its head, they imbued the young, guilt-ridden Peter Parker with the fantastic powers of an arachnid and the fantastic pressures of an everyday teenager. The combination was pure magic. Now, you can leap into Spider-Man's web-slinging world from the very beginning, including the tragic origin that started it all; the first appearances of the Daily Bugle and J. Jonah Jameson; and the debut of classic villains including the Green Goblin, Dr. Octopus, the Sandman, the Vulture and Electro! *Source: marvel.com